Vice-versa, actually. I will remove hot spots, in particular by containing the expansion of gasses and burning material, and keeping it in the proper part of the chamber, rather than having it spread everywhere. If you do that, then smooth it into the rest of the chamber, then polish the chamber up, you'll have no hot spots, which are caused by sharp edges in the combustion area. Since the location is actually a quench zone, it will force the explosion OUT of the area where you'd be adding an edge.
This increases compression, and decreases the chance for detonation, which is caused by gasses expanding in an erratic fashion (Such as in old Hemi heads, where there's no quench whatsoever). Controlling the explosion AND increasing compression is definitely a win-win to me.
Send those cams out to Crower to get reground, by the way. =) It's definitely worthwhile! And only about $200 at most.