sodium filled valves are a band-aid. Yeah, they keep the exhaust valve cooler but they up recip weight in the valvetrain, hog up valuable port space with their large shafts and are expensive to manufacture. Back in the day, when good materials were either nonexistent or hyper-costly, they were a solution but nowadays, better alternatives are available.
...and in answer to the op's question, the exhaust valves are inconel...THAT's the right maaterial for today's engines.
Darth Vader